Journalartikel

Jahr der Veröffentlichung: 2014

Seiten: 11032-11035

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 53

Heftnummer: 41

ISSN: 1433-7851

DOI Link: https://doi.org/10.1002/anie.201406112

Verlag: Wiley

Abstract: 
In the industrially important Chlor-Alkali process, the chlorine evolution reaction (CER) over a ruthenium dioxide (RuO2) catalyst competes with the oxygen evolution reaction (OER). This selectivity issue is elucidated on the microscopic level with the single-crystalline model electrode RuO2(110) by employing density functional theory (DFT) calculations in combination with the concept of volcano plots. We demonstrate that one monolayer of TiO2(110) supported on RuO2(110) enhances the selectivity towards the CER by several orders of magnitudes, while preserving the high activity for the CER. This win-win situation is attributed to the different slopes of the volcano curves for the CER and OER.

Harvard-Zitierstil: Exner, K., Anton, J., Jacob, T. and Over, H. (2014) Controlling selectivity in the chlorine evolution reaction over RuO₂-based catalysts, Angewandte Chemie International Edition, 53(41), pp. 11032-11035. https://doi.org/10.1002/anie.201406112

APA-Zitierstil: Exner, K., Anton, J., Jacob, T., & Over, H. (2014). Controlling selectivity in the chlorine evolution reaction over RuO₂-based catalysts. Angewandte Chemie International Edition. 53(41), 11032-11035. https://doi.org/10.1002/anie.201406112