Journal article

Identification of stable and metastable adsorption sites of K adsorbed on Al(111).


Authors listStampfl, C; Scheffler, M; Over, H; Burchhardt, J; Nielsen, M; Adams, DL; Moritz, W

Publication year1992

Pages1532-1535

JournalPhysical Review Letters

Volume number69

Issue number10

ISSN0031-9007

DOI Linkhttps://doi.org/10.1103/PhysRevLett.69.1532

PublisherAmerican Physical Society


Abstract

The adsorption of potassium on Al(111) at 90 K and at 300 K has been investigated by low-energy electron diffraction (LEED). Although a (√3 × √3 )R30° structure is formed at each temperature, a detailed LEED analysis has revealed that the adsorbate positions are quite different and unusual in each case. At 90 K the adatoms occupy on-top sites and at 300 K they occupy substitutional sites. An irreversible phase transformation from the former to the latter structure occurs on warming to 300 K. These results are discussed in the light of recent density-functional-theory calculations.




Authors/Editors




Citation Styles

Harvard Citation styleStampfl, C., Scheffler, M., Over, H., Burchhardt, J., Nielsen, M., Adams, D., et al. (1992) Identification of stable and metastable adsorption sites of K adsorbed on Al(111)., Physical Review Letters, 69(10), pp. 1532-1535. https://doi.org/10.1103/PhysRevLett.69.1532

APA Citation styleStampfl, C., Scheffler, M., Over, H., Burchhardt, J., Nielsen, M., Adams, D., & Moritz, W. (1992). Identification of stable and metastable adsorption sites of K adsorbed on Al(111).. Physical Review Letters. 69(10), 1532-1535. https://doi.org/10.1103/PhysRevLett.69.1532


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