Journalartikel

Jahr der Veröffentlichung: 2013

Seiten: 1034-1046

Zeitschrift: ACS Catalysis

Bandnummer: 3

Heftnummer: 5

ISSN: 2155-5435

DOI Link: https://doi.org/10.1021/cs300735e

Verlag: American Chemical Society

Abstract: 

The Deacon process is a sustainable way to recover chlorine from HCl by its oxidation with molecular oxygen. Deacon catalysts need to fulfill both selection criteria: high activity and high stability. In this Review, we introduce and discuss simple descriptors for assessing activity and stability of catalyst materials. A promising descriptor for ranking the experimental activities of Deacon catalysts and other oxidation catalysts in the form of oxides represents the dissociation energy of molecular oxygen as introduced by Studt et al. (ChemCatChem.2010, 2, 98). The resulting volcano plot allows for identifying promising catalyst materials for the Deacon process, such as exemplified with La2O3.

Harvard-Zitierstil: Over, H. and Schonmäcker, R. (2013) What Makes a Good Catalyst for the Deacon Process?, ACS Catalysis, 3(5), pp. 1034-1046. https://doi.org/10.1021/cs300735e

APA-Zitierstil: Over, H., & Schonmäcker, R. (2013). What Makes a Good Catalyst for the Deacon Process?. ACS Catalysis. 3(5), 1034-1046. https://doi.org/10.1021/cs300735e