Journal article

Preparation and Characterization of Parent Phenylphosphinidene and Its Oxidation to Phenyldioxophosphorane: The Elusive Phosphorus Analogue of Nitrobenzene


Authors list: Mardyukov, A; Niedek, D; Schreiner, PR

Publication year: 2017

Pages: 5019-5022

Journal: Journal of the American Chemical Society

Volume number: 139

Issue number: 14

DOI Link: https://doi.org/10.1021/jacs.7b01639

Publisher: American Chemical Society


Abstract: 

Triplet phenylphosphinidene was prepared by light-induced elimination of ethylene from the corresponding phenylphosphirane and was characterized by IR and UV/vis spectroscopy together with matching of its spectral data with density functional theory computations. The photolysis of phenylphosphirane in 3P-O2 doped matrices enabled the spectroscopic identification of a hitherto unknown phenyldioxophosphorane, the long elusive phosphorus analogue of nitrobenzene.




Citation Styles

Harvard Citation style: Mardyukov, A., Niedek, D. and Schreiner, P. (2017) Preparation and Characterization of Parent Phenylphosphinidene and Its Oxidation to Phenyldioxophosphorane: The Elusive Phosphorus Analogue of Nitrobenzene, Journal of the American Chemical Society, 139(14), pp. 5019-5022. https://doi.org/10.1021/jacs.7b01639

APA Citation style: Mardyukov, A., Niedek, D., & Schreiner, P. (2017). Preparation and Characterization of Parent Phenylphosphinidene and Its Oxidation to Phenyldioxophosphorane: The Elusive Phosphorus Analogue of Nitrobenzene. Journal of the American Chemical Society. 139(14), 5019-5022. https://doi.org/10.1021/jacs.7b01639


Last updated on 2025-21-05 at 13:17