Journalartikel

Jahr der Veröffentlichung: 2011

Seiten: 1175-1188

Zeitschrift: Phosphorus, Sulfur, and Silicon and the Related Elements

Bandnummer: 186

Heftnummer: 5

DOI Link: https://doi.org/10.1080/10426507.2010.540728

Verlag: Taylor and Francis Group

Abstract: 

The matrix isolation technique in combination with vacuum pyrolysis,
photochemistry, and quantum mechanical computations was applied to study
the structures and reactivities of dimethoxycarbene (DMC) and
1,3-dithian-2-ylidene. 1,2,4-Trithiolane was used for the generation of
thioformaldehyde S-sulfide and the isomeric dithiirane. Irradiation of thioformaldehyde S-oxide
in argon matrix at 10 K led to the first isolation of parent
oxathiirane as well as HCSOH, a remarkable species with a rare formal
carbon–sulfur triple bond.

Harvard-Zitierstil: Mloston, G., Romanski, J., Reisenauer, H. and Schreiner, P. (2011) Matrix Isolation Studies on Sulfur Heterocycles and Related Species, Phosphorus, Sulfur, and Silicon and the Related Elements, 186(5), pp. 1175-1188. https://doi.org/10.1080/10426507.2010.540728

APA-Zitierstil: Mloston, G., Romanski, J., Reisenauer, H., & Schreiner, P. (2011). Matrix Isolation Studies on Sulfur Heterocycles and Related Species. Phosphorus, Sulfur, and Silicon and the Related Elements. 186(5), 1175-1188. https://doi.org/10.1080/10426507.2010.540728