Journalartikel

Jahr der Veröffentlichung: 2010

Seiten: 2132-2137

Zeitschrift: European Journal of Organic Chemistry

Bandnummer: 2010

Heftnummer: 11

DOI Link: https://doi.org/10.1002/ejoc.200901440

Verlag: Wiley

Abstract: 

The products of the gas‐phase pyrolysis of two regioisomeric 1,2,4‐trithiolane S‐oxides
were collected in an argon matrix at 10 K and studied by means of
spectroscopic as well as computational methods. Whereas the main
products of the pyrolysis of the “symmetrical” S‐oxide were identified asthioformaldehyde S‐oxide and thioformaldehyde S‐sulfide, the “non‐symmetrical” S‐oxide gave predominantly dithioformic acid, which exists as a mixture of s‐cis and s‐trans conformers. We present a rationalization of the reaction pathways including density functional theory computations.

Harvard-Zitierstil: Mloston, G., Romanski, J., McKee, M., Reisenauer, H. and Schreiner, P. (2010) Thermal Reactions of Regioisomeric 1,2,4‐Trithiolane S‐Oxides, European Journal of Organic Chemistry, 2010(11), pp. 2132-2137. https://doi.org/10.1002/ejoc.200901440

APA-Zitierstil: Mloston, G., Romanski, J., McKee, M., Reisenauer, H., & Schreiner, P. (2010). Thermal Reactions of Regioisomeric 1,2,4‐Trithiolane S‐Oxides. European Journal of Organic Chemistry. 2010(11), 2132-2137. https://doi.org/10.1002/ejoc.200901440