Mechanisms of the C-H halogenation of adamantane in the presence of N-hydroxyphthalimide - Research portal of Justus Liebig University Giessen:

Journal article

Mechanisms of the C-H halogenation of adamantane in the presence of N-hydroxyphthalimide

Authors list: Zhuk, TS; Gunchenko, PA; Korovai, YY; Schreiner, PR; Fokin, AA

Publication year: 2008

Pages: 48-

Journal: Theoretical and Experimental Chemistry

Volume number: 2008

Issue number: 44

DOI Link: https://doi.org/10.1007/s11237-008-9000-6

Publisher: Springer

Abstract:

A study was carried out on the mechanisms for the halogenation of the
C-H bonds in systems containing N-hydroxyphthalimide, oxone, and CHal₄
or N-hydroxyphthalimide and t-BuOCl. These reactions proceed with the
participation of the phthalimido-N-oxyl (PINO) radical, which may serve
either as an initiator or reagent. A DFT (density functional theory)
model showed that the PINO radical may be generated efficiently in the
presence of t-BuOCl as the initiator.

Authors/Editors

- Uni.-Prof. Dr. Peter Richard Schreiner, PhD

Citation Styles

Harvard Citation style: Zhuk, T., Gunchenko, P., Korovai, Y., Schreiner, P. and Fokin, A. (2008) Mechanisms of the C-H halogenation of adamantane in the presence of N-hydroxyphthalimide, Theoretical and Experimental Chemistry, 2008(44), p. 48. https://doi.org/10.1007/s11237-008-9000-6

APA Citation style: Zhuk, T., Gunchenko, P., Korovai, Y., Schreiner, P., & Fokin, A. (2008). Mechanisms of the C-H halogenation of adamantane in the presence of N-hydroxyphthalimide. Theoretical and Experimental Chemistry. 2008(44), 48. https://doi.org/10.1007/s11237-008-9000-6