Journalartikel

Jahr der Veröffentlichung: 2008

Seiten: 7071-7074

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 47

Heftnummer: 37

DOI Link: https://doi.org/10.1002/anie.200802105

Verlag: Wiley

Abstract: 

Out and about: CO₂ extrusion from simple α‐keto
carboxylic acids can be used to prepare hitherto unknown
hydroxycarbenes. High‐vacuum flash pyrolysis of oxalic acid or its
monomethyl ester enabled the preparation and characterization of
dihydroxy‐ (1) and hydroxymethoxycarbene, respectively, both of
which are stabilized through π‐type out‐of‐plane and in‐plane
σ conjugation (the HOMO of s‐trans,s‐trans‐1 is shown).

Harvard-Zitierstil: Schreiner, P. and Reisenauer, H. (2008) Spectroscopic Identification of Dihydroxycarbene, Angewandte Chemie International Edition, 47(37), pp. 7071-7074. https://doi.org/10.1002/anie.200802105

APA-Zitierstil: Schreiner, P., & Reisenauer, H. (2008). Spectroscopic Identification of Dihydroxycarbene. Angewandte Chemie International Edition. 47(37), 7071-7074. https://doi.org/10.1002/anie.200802105