Journal article

Publication year: 2008

Pages: 2998-3003

Journal: European Journal of Organic Chemistry

Volume number: 2008

Issue number: 17

DOI Link: https://doi.org/10.1002/ejoc.200800023

Publisher: Wiley

Abstract: 

The flash‐vacuum pyrolysis of selected dispirodicycloaliphatic
1,2,4‐trithiolanes was studied by using matrix isolation techniques. The
formation of thiosulfines and dithiiranes along with the corresponding
thioketones was detected spectroscopically and confirmed by comparison
with computed spectra. In the case of tetramethylcyclobutanone
1,2,4‐trithiolane, the thermal formation of the dithiolactone was
observed. Pyrolysis of the (dichloro)tetramethylcyclobutane derivative
resulted only in the formation of a mixture of the thiosulfine and
dithiirane. In this case, conversion into the corresponding
dithiolactone could be achieved photochemically. The dispirodiadamantane
derivative gave a mixture of the respective thiosulfine and dithiirane
but no dithiolactone could be detected in the mixture.

Harvard Citation style: Romanski, J., Reisenauer, H., Petzold, H., Weigand, W., Schreiner, P. and Mloston, G. (2008) Generation and Rearrangement of Some Spirocycloaliphatic Thiosulfines and Dithiiranes, European Journal of Organic Chemistry, 2008(17), pp. 2998-3003. https://doi.org/10.1002/ejoc.200800023

APA Citation style: Romanski, J., Reisenauer, H., Petzold, H., Weigand, W., Schreiner, P., & Mloston, G. (2008). Generation and Rearrangement of Some Spirocycloaliphatic Thiosulfines and Dithiiranes. European Journal of Organic Chemistry. 2008(17), 2998-3003. https://doi.org/10.1002/ejoc.200800023