Journalartikel

Jahr der Veröffentlichung: 2018

Seiten: 6930-6934

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 57

Heftnummer: 23

ISSN: 1433-7851

Open Access Status: Green

DOI Link: https://doi.org/10.1002/anie.201713197

Verlag: Wiley

Abstract: 
The complex of [10]cycloparaphenylene ([10]CPP) with bis(azafullerene) (C59N)(2) is investigated experimentally and computationally. Two [10]CPP rings are bound to the dimeric azafullerene giving [10]CPP superset of (C59N)(2) subset of [10] CPP. Photophysical and redox properties support an electronic interaction between the components especially when the second [10]CPP is bound. Unlike [10] CPP $ C60, in which there is negligible electronic communication between the two species, upon photoexcitation a partial charge transfer phenomenon is revealed between [10]CPP and (C59N) 2 reminiscent of CPP-encapsulated metallofullerenes. Such an alternative electronrich fullerene species demonstrates C60-like ground-state properties and metallofullerene-like excited-state properties opening new avenues for construction of functional supramolecular architectures with organic materials.

Harvard-Zitierstil: Rio, J., Beeck, S., Rotas, G., Ahles, S., Jacquemin, D., Tagmatarchis, N., et al. (2018) Electronic Communication between two [10]cycloparaphenylenes and Bis(azafullerene) (C59N)(2) Induced by Cooperative Complexation, Angewandte Chemie International Edition, 57(23), pp. 6930-6934. https://doi.org/10.1002/anie.201713197

APA-Zitierstil: Rio, J., Beeck, S., Rotas, G., Ahles, S., Jacquemin, D., Tagmatarchis, N., Ewels, C., & Wegner, H. (2018). Electronic Communication between two [10]cycloparaphenylenes and Bis(azafullerene) (C59N)(2) Induced by Cooperative Complexation. Angewandte Chemie International Edition. 57(23), 6930-6934. https://doi.org/10.1002/anie.201713197