Journalartikel

Synthesis of Substituted [8]Cycloparaphenylenes by [2+2+2] Cycloaddition


AutorenlisteTran-Van, AF; Huxol, E; Basler, JM; Neuburger, M; Adjizian, JJ; Ewels, CP; Wegner, HA

Jahr der Veröffentlichung2014

Seiten1594-1597

ZeitschriftOrganic Letters

Bandnummer16

Heftnummer6

ISSN1523-7060

DOI Linkhttps://doi.org/10.1021/ol500194s

VerlagAmerican Chemical Society


Abstract
A new modular approach to the smallest substituted cycloparaphenylenes (CPPs) is presented. This versatile method permits access to substituted CPPs, choosing the substituent at a late stage of the synthesis. Variously substituted [8]CPPs have been synthesized, and their properties analyzed. The structural characteristics of substituted CPPs are close to those of unsubstituted CPPs. However, their optoelectronic behavior differs remarkably due to the larger torsion angle between the phenyl units.



Zitierstile

Harvard-ZitierstilTran-Van, A., Huxol, E., Basler, J., Neuburger, M., Adjizian, J., Ewels, C., et al. (2014) Synthesis of Substituted [8]Cycloparaphenylenes by [2+2+2] Cycloaddition, Organic Letters, 16(6), pp. 1594-1597. https://doi.org/10.1021/ol500194s

APA-ZitierstilTran-Van, A., Huxol, E., Basler, J., Neuburger, M., Adjizian, J., Ewels, C., & Wegner, H. (2014). Synthesis of Substituted [8]Cycloparaphenylenes by [2+2+2] Cycloaddition. Organic Letters. 16(6), 1594-1597. https://doi.org/10.1021/ol500194s


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