Transition metal-catalyzed intermolecular [5+2] and [5+2+1] cycloadditions of allenes and vinylcyclopropanes - Forschungsportal der Justus-Liebig-Universität Gießen:

Journal article

Transition metal-catalyzed intermolecular [5+2] and [5+2+1] cycloadditions of allenes and vinylcyclopropanes

Authors list: Wegner, HA; de Meijere, A; Wender, PA

Publication year: 2005

Pages: 6530-6531

Journal: Journal of the American Chemical Society

Volume number: 127

Issue number: 18

ISSN: 0002-7863

DOI Link: https://doi.org/10.1021/ja043671w

Publisher: American Chemical Society

Abstract:

Initial examples of the intermolecular Rh(I)-catalyzed [5+2] cycloaddition reaction of bifunctional allenes and vinylcyclopropanes are described. The reactions proceed with facility and in yields of up to 99% with a variety of alkyne-, ester-, styrene-, or cyano-substituents on the allene to afford the corresponding cycloadducts. In the presence of CO, the reaction proceeds to an eight-membered ring cycloadduct and its transannularly closed product, providing the first example of a three-component [5+2+1] cycloaddition with allenes.

Authors/Editors

- Uni.-Prof. Dr. Hermann Andreas Wegner

Citation Styles

Harvard Citation style: Wegner, H., de Meijere, A. and Wender, P. (2005) Transition metal-catalyzed intermolecular [5+2] and [5+2+1] cycloadditions of allenes and vinylcyclopropanes, Journal of the American Chemical Society, 127(18), pp. 6530-6531. https://doi.org/10.1021/ja043671w

APA Citation style: Wegner, H., de Meijere, A., & Wender, P. (2005). Transition metal-catalyzed intermolecular [5+2] and [5+2+1] cycloadditions of allenes and vinylcyclopropanes. Journal of the American Chemical Society. 127(18), 6530-6531. https://doi.org/10.1021/ja043671w