Journal article

Silicon-(Thio)urea Lewis Acid Catalysis


Authors listHrdina, R; Müller, CE; Wende, RC; Lippert, KM; Benassi, M; Spengler, B; Schreiner, PR

Publication year2011

Pages7624-7627

JournalJournal of the American Chemical Society

Volume number133

Issue number20

ISSN0002-7863

DOI Linkhttps://doi.org/10.1021/ja110685k

PublisherAmerican Chemical Society


Abstract
We present a new class of catalysts based on the combination of N,N'-diaryl(thio)ureas and weak silicon Lewis acids (e.g., SiCl(4)). Such silicon-(thio)urea catalysts effectively catalyze the stereospecific rearrangement of epoxides to quaternary carbaldehydes.



Citation Styles

Harvard Citation styleHrdina, R., Müller, C., Wende, R., Lippert, K., Benassi, M., Spengler, B., et al. (2011) Silicon-(Thio)urea Lewis Acid Catalysis, Journal of the American Chemical Society, 133(20), pp. 7624-7627. https://doi.org/10.1021/ja110685k

APA Citation styleHrdina, R., Müller, C., Wende, R., Lippert, K., Benassi, M., Spengler, B., & Schreiner, P. (2011). Silicon-(Thio)urea Lewis Acid Catalysis. Journal of the American Chemical Society. 133(20), 7624-7627. https://doi.org/10.1021/ja110685k


Last updated on 2025-21-05 at 13:21