Journal article

Synthesis, characterization and properties of iron(II) complexes with a series of tripodal ligands based on the parent ligand tris(2-pyridylmethyl)amine


Authors listKisslinger, S; Kelm, H; Beitat, A; Wurtele, C; Kruger, HJ; Schindler, S

Publication year2011

Pages540-545

JournalInorganica Chimica Acta

Volume number374

Issue number1

ISSN0020-1693

DOI Linkhttps://doi.org/10.1016/j.ica.2011.02.062

PublisherElsevier


Abstract
Iron(II) complexes of the type [Fe(L)(NCS)(2)] with the tripodal ligand apme (apme = N-1-(2-aminoethyl)-N-1-(2-pyridyl-methyl)-1,2-ethanediamine) as well as with its derivatives were prepared and structurally characterized. The bond distances thus obtained showed that all complexes investigated were high-spin at the respective temperature. Furthermore [Fe(Me(4)apme)(NCS)(2)] was analyzed using Mossbauer spectroscopy that showed that this complex remains in its high-spin state over the entire temperature range. (C) 2011 Elsevier B. V. All rights reserved.



Citation Styles

Harvard Citation styleKisslinger, S., Kelm, H., Beitat, A., Wurtele, C., Kruger, H. and Schindler, S. (2011) Synthesis, characterization and properties of iron(II) complexes with a series of tripodal ligands based on the parent ligand tris(2-pyridylmethyl)amine, Inorganica Chimica Acta, 374(1), pp. 540-545. https://doi.org/10.1016/j.ica.2011.02.062

APA Citation styleKisslinger, S., Kelm, H., Beitat, A., Wurtele, C., Kruger, H., & Schindler, S. (2011). Synthesis, characterization and properties of iron(II) complexes with a series of tripodal ligands based on the parent ligand tris(2-pyridylmethyl)amine. Inorganica Chimica Acta. 374(1), 540-545. https://doi.org/10.1016/j.ica.2011.02.062


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