Journalartikel

Jahr der Veröffentlichung: 2015

Seiten: 12404-12409

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 54

Heftnummer: 42

DOI Link: https://doi.org/10.1002/anie.201501844

Verlag: Wiley

Abstract: 

We report the evaporation of a stable cyclic silylene and its oxidation (with ozone or N₂O)
through oxygen atom transfer to form the corresponding silanone under
matrix isolation conditions. As uncomplexed silanones are rare owing to
their very high reactivity, this method provides an alternative route to
these sought‐after molecules. The silanone, as well as a novel bicyclic
silane with a bridgehead silicon atom derived from an intramolecular
silylene CH bond insertion, were characterized by comparison of
high‐resolution infrared spectra with density functional theory (DFT)
computations at the M06‐2X/cc‐pVDZ level of theory.

Harvard-Zitierstil: Linden, M., Reisenauer, H., Gerbig, D., Karni, M., Schäfer, A., Müller, T., et al. (2015) Preparation of a Silanone through Oxygen Atom Transfer to a Stable Cyclic Silylene, Angewandte Chemie International Edition, 54(42), pp. 12404-12409. https://doi.org/10.1002/anie.201501844

APA-Zitierstil: Linden, M., Reisenauer, H., Gerbig, D., Karni, M., Schäfer, A., Müller, T., Apeloig, Y., & Schreiner, P. (2015). Preparation of a Silanone through Oxygen Atom Transfer to a Stable Cyclic Silylene. Angewandte Chemie International Edition. 54(42), 12404-12409. https://doi.org/10.1002/anie.201501844