Journalartikel

Jahr der Veröffentlichung: 2011

Seiten: 12639-12642

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 50

Heftnummer: 52

ISSN: 1433-7851

DOI Link: https://doi.org/10.1002/anie.201103615

Verlag: Wiley

Abstract: 

Hexaphenylethane is unstable, a phenomenon traditionally attributed to
steric repulsion between the six phenyl rings. However, adding 12 bulky tert‐butyl groups, one to each of the 12 meta
positions, gives a stabile ethane derivative (see space‐filling model
and potential energy curve for the dissociation of the central CC
bond). This unexpected stabilization is shown to result from attractive
dispersion interactions between the substituents.

Harvard-Zitierstil: Grimme, S. and Schreiner, P. (2011) Steric Crowding Can Stabilize a Labile Molecule: Solving the Hexaphenylethane Riddle, Angewandte Chemie International Edition, 50(52), pp. 12639-12642. https://doi.org/10.1002/anie.201103615

APA-Zitierstil: Grimme, S., & Schreiner, P. (2011). Steric Crowding Can Stabilize a Labile Molecule: Solving the Hexaphenylethane Riddle. Angewandte Chemie International Edition. 50(52), 12639-12642. https://doi.org/10.1002/anie.201103615