Journalartikel

Jahr der Veröffentlichung: 2009

Seiten: 9647-9650

Zeitschrift: Chemistry - A European Journal

Bandnummer: 15

Heftnummer: 38

ISSN: 0947-6539

DOI Link: https://doi.org/10.1002/chem.200901711

Verlag: Wiley

Abstract: 

Short lipophilic oligopeptides utilizing nucleophilic N‐π‐methyl histidine residues catalyze the desymmetrization of meso‐1,2‐diols
with enantiomeric ratios of up to 94:6. Direct one‐pot oxidation, which
avoids the well‐known racemization of the monoacylated product,
directly leads to α‐acetoxy ketones with enantiomeric ratios of up to
97:3 and 97 % yield.

Harvard-Zitierstil: Müller, C., Zell, D. and Schreiner, P. (2009) One‐Pot Desymmetrization of meso‐1,2‐Hydrocarbon Diols through Acylation and Oxidation, Chemistry - A European Journal, 15(38), pp. 9647-9650. https://doi.org/10.1002/chem.200901711

APA-Zitierstil: Müller, C., Zell, D., & Schreiner, P. (2009). One‐Pot Desymmetrization of meso‐1,2‐Hydrocarbon Diols through Acylation and Oxidation. Chemistry - A European Journal. 15(38), 9647-9650. https://doi.org/10.1002/chem.200901711