Journalartikel

Jahr der Veröffentlichung: 2008

Seiten: 8696-8699

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 47

Heftnummer: 45

DOI Link: https://doi.org/10.1002/anie.200803487

Verlag: Wiley

Abstract: 

The road less traveled does indeed make all the difference. The
reaction of oxyallylic cations with cyclopentadiene usually yields a
[4+3] cycloadduct. Instead, a hydride shift can supersede this
cycloadditon process and proceed in synthetically useful yields (see
scheme). Computational analyses suggest that substantial electronic
effects influence the “road” taken by the oxyallylic cation.

Harvard-Zitierstil: Harmata, M., Huang, C., Rooshenas, P. and Schreiner, P. (2008) An Interrupted [4+3] Cycloaddition Reaction: A Hydride Shift (Ene Reaction) Intervenes, Angewandte Chemie International Edition, 47(45), pp. 8696-8699. https://doi.org/10.1002/anie.200803487

APA-Zitierstil: Harmata, M., Huang, C., Rooshenas, P., & Schreiner, P. (2008). An Interrupted [4+3] Cycloaddition Reaction: A Hydride Shift (Ene Reaction) Intervenes. Angewandte Chemie International Edition. 47(45), 8696-8699. https://doi.org/10.1002/anie.200803487