Journalartikel

Jahr der Veröffentlichung: 2012

Seiten: 877-883

Zeitschrift: Beilstein Journal of Organic Chemistry

Bandnummer: 8

ISSN: 1860-5397

DOI Link: https://doi.org/10.3762/bjoc.8.99

Verlag: Beilstein-Institut

Abstract: 
The investigation of multi-photochromic compounds constitutes a great challenge, not only from a synthetic point of view, but also with respect to the analysis of the photochemical properties. In this context we designed a novel strategy to access meta-oligoazobiphenyls via site-selective Mills reaction and Suzuki cross-coupling in a highly efficient iterative way. Photochemical examination of the resulting monomeric and oligomeric azo compounds revealed that the overall degree of switching was independent of the connected azo-units. However, one of the azobonds in the bis-azobiphenyl is isomerized preferentially despite the high structural similarity.

Harvard-Zitierstil: Reuter, R. and Wegner, H. (2012) meta-Oligoazobiphenyls - synthesis via site-selective Mills reaction and photochemical properties, Beilstein Journal of Organic Chemistry, 8, pp. 877-883. https://doi.org/10.3762/bjoc.8.99

APA-Zitierstil: Reuter, R., & Wegner, H. (2012). meta-Oligoazobiphenyls - synthesis via site-selective Mills reaction and photochemical properties. Beilstein Journal of Organic Chemistry. 8, 877-883. https://doi.org/10.3762/bjoc.8.99