Journal article

Publication year: 2013

Pages: 1700-1706

Journal: Chemie Ingenieur Technik

Volume number: 85

Issue number: 11

ISSN: 0009-286X

DOI Link: https://doi.org/10.1002/cite.201300079

Publisher: Wiley

Abstract: 
1,4-Bis(trimethoxysilyl)benzene and 1,4-bis((trimethoxysilyl)-phenyl)-dimethoxysilane were synthesized from their corresponding diarylbromides. These bis(trimethoxysilyl)arenes were used as organosilica precursors for the preparation of macro-/mesoporous silica monoliths, using poly(ethylen glycol) as a porogen to obtain a well-defined bicontinuous macroporosity and mesoporosity. The porosity of the prepared materials was characterized by nitrogen sorption measurements, mercury intrusion and scanning electron microscopy. The incorporation of silylarenes was studied by solid-state (CNMR)-C-13 spectroscopy, IR spectroscopy and elemental analysis.

Harvard Citation style: von der Lehr, M., Weidmann, C., Mascotto, S. and Smarsly, B. (2013) Hierarchically Ordered Monolithic Silica with Bimodal Porosity Obtained by Hydrolysis and Condensation of 1,4-Bis(trimethoxysilyl)arenes, Chemie Ingenieur Technik, 85(11), pp. 1700-1706. https://doi.org/10.1002/cite.201300079

APA Citation style: von der Lehr, M., Weidmann, C., Mascotto, S., & Smarsly, B. (2013). Hierarchically Ordered Monolithic Silica with Bimodal Porosity Obtained by Hydrolysis and Condensation of 1,4-Bis(trimethoxysilyl)arenes. Chemie Ingenieur Technik. 85(11), 1700-1706. https://doi.org/10.1002/cite.201300079