Journal article

Publication year: 2009

Pages: 5300-5306

Journal: Chemistry of Materials

Volume number: 21

Issue number: 21

ISSN: 0897-4756

DOI Link: https://doi.org/10.1021/cm9024167

Publisher: American Chemical Society

Abstract: 
A novel method for the preparation of hierarchically porous LiFePO4 electrode materials for lithium ion batteries has been investigated. A meso/microporous carbon monolith, a conductive framework, was prepared and infiltrated with the LiFePO4 precursors to increase the electrode/electrolyte interface and improve the rate capability of the battery. The final LiFePO4/carbon monoliths feature a meso/macroporous hierarchical structure. The monoliths we:c calcined at increasing temperatures, from 650 to 800 degrees C, to determine the structural and sintering effects on the electrochemical properties of the materials The samples were characterized using SEM, TEM, nitrogen sorption, and XRD analysis prior to electrochemical testing. The results showed that the capacity of the LiFePO4/carbon electrodes achieved 82% of the theoretical capacity at 0.1C discharge rate.

Harvard Citation style: Doherty, C., Caruso, R., Smarsly, B., Adelhelm, P. and Drummond, C. (2009) Hierarchically Porous Monolithic LiFePO4/Carbon Composite Electrode Materials for High Power Lithium Ion Batteries, Chemistry of Materials, 21(21), pp. 5300-5306. https://doi.org/10.1021/cm9024167

APA Citation style: Doherty, C., Caruso, R., Smarsly, B., Adelhelm, P., & Drummond, C. (2009). Hierarchically Porous Monolithic LiFePO4/Carbon Composite Electrode Materials for High Power Lithium Ion Batteries. Chemistry of Materials. 21(21), 5300-5306. https://doi.org/10.1021/cm9024167