Journalartikel

Jahr der Veröffentlichung: 2009

Seiten: 7544-7545

Zeitschrift: Journal of the American Chemical Society

Bandnummer: 131

Heftnummer: 22

ISSN: 0002-7863

DOI Link: https://doi.org/10.1021/ja902327s

Verlag: American Chemical Society

Abstract: 
Dinuclear copper peroxo complexes obtained from mononuclear copper(I) complexes showed extremely high stabilities under ambient conditions in the solid state and could be heated above 100 degrees C without decomposition. The increased stability could be explained with regard to their molecular structures. Furthermore, the four complexes investigated showed a high potential for aliphatic C-H bond oxidations: for example, technical-grade toluene was oxidized to benzaldehyde in yields of up to 20%.

Harvard-Zitierstil: Würtele, C., Sander, O., Lutz, V., Waitz, T., Tuczek, F. and Schindler, S. (2009) Aliphatic C-H bond oxidation of toluene using copper peroxo complexes that are stable at room temperature, Journal of the American Chemical Society, 131(22), pp. 7544-7545. https://doi.org/10.1021/ja902327s

APA-Zitierstil: Würtele, C., Sander, O., Lutz, V., Waitz, T., Tuczek, F., & Schindler, S. (2009). Aliphatic C-H bond oxidation of toluene using copper peroxo complexes that are stable at room temperature. Journal of the American Chemical Society. 131(22), 7544-7545. https://doi.org/10.1021/ja902327s