Journalartikel

Jahr der Veröffentlichung: 2008

Seiten: 82-85

Zeitschrift: Angewandte Chemie International Edition

Bandnummer: 47

Heftnummer: 1

ISSN: 1433-7851

DOI Link: https://doi.org/10.1002/anie.200704389

Verlag: Wiley

Abstract: 

Donor makes the difference: The mononuclear η¹‐superoxo copper(II) complex 1 undergoes dioxygen activation with the addition of hydrogen‐atom donors. Net O₂‐derived O‐atom insertion into the N‐methyl group of the ligand leads to formation of a copper(II)‐alkoxide product 2. The cupric superoxo species 1 itself is not capable of the observed hydroxylation reaction.

Harvard-Zitierstil: Maiti, D., Lee, D., Gaoutchenova, K., Würtele, C., Holthausen, M., Sarjeant, A., et al. (2008) Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation : modeling copper-monooxygenase C-H hydroxylation, Angewandte Chemie International Edition, 47(1), pp. 82-85. https://doi.org/10.1002/anie.200704389

APA-Zitierstil: Maiti, D., Lee, D., Gaoutchenova, K., Würtele, C., Holthausen, M., Sarjeant, A., Sundermeyer, J., Schindler, S., & Karlin, K. (2008). Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation : modeling copper-monooxygenase C-H hydroxylation. Angewandte Chemie International Edition. 47(1), 82-85. https://doi.org/10.1002/anie.200704389