Journalartikel

Jahr der Veröffentlichung: 1997

Seiten: 709-716

Zeitschrift: Journal of thermal analysis

Bandnummer: 48

Heftnummer: 4

ISSN: 0368-4466

DOI Link: https://doi.org/10.1007/BF01997176

Verlag: Heyden

Abstract: 
Annealing of ZrO2 in a nitrogen atmosphere leads to a nitrogen containing phase called beta '' phase having a trigonally distorted fluorite structure with ordered anion vacancies. DTA/TG investigations indicated that the beta '' phase decomposes into m-ZrO2 above 500 degrees C releasing nitrogen during the reaction with oxygen. Prevention of oxygen uptake by use of closed tantalum tubes instead of open platinum crucibles enabled the detection of a new reversible phase transition at similar to 965 degrees C. The thermoanalytical results have been confirmed by high temperature-X-ray investigation.

Harvard-Zitierstil: Walter, D., Lerch, M. and Laqua, W. (1997) Thermal stability of the β″ phase in the ZrO2-Zr3N4 system, Journal of thermal analysis, 48(4), pp. 709-716. https://doi.org/10.1007/BF01997176

APA-Zitierstil: Walter, D., Lerch, M., & Laqua, W. (1997). Thermal stability of the β″ phase in the ZrO2-Zr3N4 system. Journal of thermal analysis. 48(4), 709-716. https://doi.org/10.1007/BF01997176