Journal article

Publication year: 2012

Pages: 2069-2077

Journal: Journal of Inorganic and General Chemistry

Volume number: 638

Issue number: 12-13

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.201200237

Publisher: Wiley

Abstract: 
A series of iron(II) dithiocyanate complexes containing the tripodal ligands L, [Fe(L)(NCS)(2)] (with L = 6-Me(2)tmpa, 6-Me(2)pmea, 6-Me-2-Me(2)uns-penp, 6-Me-2-uns-penp, Me(2)uns-penp, imine-uns-penp and TMG-uns-penp), analogous to the known SCO complex[Fe(tmpa)(NCS)(2)] were prepared and investigated. It was possible to structurally characterize [Fe(6-Me(2)pmea)(NCS)(2)], [Fe(6-Me-2-Me(2)uns-penp)(NCS)(2)], [Fe(Me(2)uns-penp)(NCS)(2)], [Fe(imine-uns-penp)(NCS)(2)] and [Fe(TMG-uns-penp)(NCS)(2)]. Magnetic susceptibility and Mossbauer measurements showed that all seven compounds maintain their high-spin states between 300 and 5 K.

Harvard Citation style: Kisslinger, S., Kelm, H., Zheng, S., Beitat, A., Wurtele, C., Wortmann, R., et al. (2012) Synthesis and Characterization of Iron(II) Thiocyanate Complexes with Derivatives of the Tris(pyridine-2-ylmethyl)amine (tmpa) Ligand, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 638(12-13), pp. 2069-2077. https://doi.org/10.1002/zaac.201200237

APA Citation style: Kisslinger, S., Kelm, H., Zheng, S., Beitat, A., Wurtele, C., Wortmann, R., Bonnet, S., Herres-Pawlis, S., Kruger, H., & Schindler, S. (2012). Synthesis and Characterization of Iron(II) Thiocyanate Complexes with Derivatives of the Tris(pyridine-2-ylmethyl)amine (tmpa) Ligand. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 638(12-13), 2069-2077. https://doi.org/10.1002/zaac.201200237