Kinetic Studies on the Hydrogenation of Carbon Dioxide to Formic Acid using a Rhodium Complex as Catalyst - Research portal of Justus Liebig University Giessen:

Journal article

Kinetic Studies on the Hydrogenation of Carbon Dioxide to Formic Acid using a Rhodium Complex as Catalyst

Authors list: Dietrich, J; Schindler, S

Publication year: 2008

Pages: 2487-2494

Journal: Journal of Inorganic and General Chemistry

Volume number: 634

Issue number: 14

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.200800352

Publisher: Wiley

Abstract:
A detailed kinetic analysis has been performed on the hydrogenation or carbon dioxide with the complex [(dppp)(2)RhH] (dppp = 1,3-bis(diphenyl-phosphino)propane in DMSO using stopped-now techniques. Activation parameters including the activation volume for this reaction as well as for the related reaction of the formation of the dihydrogen complex [(dPPP)(2)RhH2]HCO2 were obtained and thus allowed the formulation of a mechanism for this reaction cycle.

Authors/Editors

- Uni.-Prof. Dr. Siegfried Adolf Schindler

Citation Styles

Harvard Citation style: Dietrich, J. and Schindler, S. (2008) Kinetic Studies on the Hydrogenation of Carbon Dioxide to Formic Acid using a Rhodium Complex as Catalyst, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 634(14), pp. 2487-2494. https://doi.org/10.1002/zaac.200800352

APA Citation style: Dietrich, J., & Schindler, S. (2008). Kinetic Studies on the Hydrogenation of Carbon Dioxide to Formic Acid using a Rhodium Complex as Catalyst. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 634(14), 2487-2494. https://doi.org/10.1002/zaac.200800352