Journalartikel

The 3×1-Li to 7×7 structural transformation of Si(111) due to Li desorption


AutorenlisteKleine, H; Bludau, H; Over, H; Fick, D

Jahr der Veröffentlichung1998

Seiten15-20

ZeitschriftSurface Science

Bandnummer410

Heftnummer1

DOI Linkhttps://doi.org/10.1016/S0039-6028(98)00287-8

VerlagElsevier


Abstract

A combined investigation using thermal desorption spectroscopy (TDS) and low-energy electron diffraction (LEED) shows that the area of the Li-induced 3×1 reconstruction on Si(111) depends linearly on the amount of adsorbed Li. This is in contrast to the concept of an impurity-stabilized 3×1 reconstruction by a small amount of Li through a long-ranged mechanism. The desorption energy of the Li atoms involved in the reconstruction is 3.2 eV. This is substantially higher than that of Li desorbing from the Si(111)7×7 surface (2.5 eV). The high desorption energy points to saturation of dangling bonds by Li chemisorption, which also explains the passivation of the Si(111)3×1–Li surface against oxidation.




Autoren/Herausgeber




Zitierstile

Harvard-ZitierstilKleine, H., Bludau, H., Over, H. and Fick, D. (1998) The 3×1-Li to 7×7 structural transformation of Si(111) due to Li desorption, Surface Science, 410(1), pp. 15-20. https://doi.org/10.1016/S0039-6028(98)00287-8

APA-ZitierstilKleine, H., Bludau, H., Over, H., & Fick, D. (1998). The 3×1-Li to 7×7 structural transformation of Si(111) due to Li desorption. Surface Science. 410(1), 15-20. https://doi.org/10.1016/S0039-6028(98)00287-8


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