Journal article
Authors list: Fokin, AA; Schreiner, PR; Kozhushkov, SI; Sattelmeyer, KW; Schaefer, HF; de Meijere, A
Publication year: 2003
Pages: 697-700
Journal: Organic Letters
Volume number: 5
Issue number: 5
ISSN: 1523-7060
DOI Link: https://doi.org/10.1021/ol027479f
Publisher: American Chemical Society
Abstract:
Highly symmetric aliphatic hydrocarbons such as D(4h)-[4]rotane do not necessarily have degenerate HOMOs. According to our predictions based on high-level computations, its radical cation should display a highly delocalized D(4h)-symmetric structure, in contrast to its Jahn-Teller distorted cousin, the radical cation of [3]rotane, which exists in two distonic localized forms with C(2v) and C(s) symmetry.
Citation Styles
Harvard Citation style: Fokin, A., Schreiner, P., Kozhushkov, S., Sattelmeyer, K., Schaefer, H. and de Meijere, A. (2003) Delocalizations in sigma-radical cations: The intriguing structures of ionized [n]rotanes, Organic Letters, 5(5), pp. 697-700. https://doi.org/10.1021/ol027479f
APA Citation style: Fokin, A., Schreiner, P., Kozhushkov, S., Sattelmeyer, K., Schaefer, H., & de Meijere, A. (2003). Delocalizations in sigma-radical cations: The intriguing structures of ionized [n]rotanes. Organic Letters. 5(5), 697-700. https://doi.org/10.1021/ol027479f
