Journalartikel
The first efficient iodination of unactivated aliphatic hydrocarbons
Autorenliste: Schreiner, PR; Lauenstein, O; Butova, ED; Fokin, AA
Jahr der Veröffentlichung: 1999
Seiten: 2786-2788
Zeitschrift: Angewandte Chemie International Edition
Bandnummer: 38
Heftnummer: 18
ISSN: 1433-7851
Verlag: Wiley
No heavy metals, no enzymes, and a simple protocol: the direct
Abstract:
iodination of aliphatic hydrocarbons, which has not been possible to
date, can now be carried out in multiphase systems [see for example Eq.
(1)]. In situ generated tetraiodomethane serves as a key intermediate in
this selective radical chain reaction initiated by a single electron
transfer. This room‐temperature, efficient transformation is highly
regioselective, easy to work‐up, and hence widely applicable.
Zitierstile
Harvard-Zitierstil: Schreiner, P., Lauenstein, O., Butova, E. and Fokin, A. (1999) The first efficient iodination of unactivated aliphatic hydrocarbons, Angewandte Chemie International Edition, 38(18), pp. 2786-2788. https://doi.org/10.1002/(SICI)1521-3773(19990917)38:18<2786::AID-ANIE2786>3.3.CO;2-S
APA-Zitierstil: Schreiner, P., Lauenstein, O., Butova, E., & Fokin, A. (1999). The first efficient iodination of unactivated aliphatic hydrocarbons. Angewandte Chemie International Edition. 38(18), 2786-2788. https://doi.org/10.1002/(SICI)1521-3773(19990917)38:18<2786::AID-ANIE2786>3.3.CO;2-S
