Journal article
Authors list: Bui, BH; Schreiner, PR
Publication year: 2006
Pages: 4187-4192
Journal: European Journal of Organic Chemistry
Volume number: 2006
Issue number: 18
ISSN: 1434-193X
DOI Link: https://doi.org/10.1002/ejoc.200600270
Publisher: Wiley
Abstract:
A systematic application of the BLYP/6-311+G*//BLYP/6-31G* computational scheme was utilized to identify the favored aromatic 2,6-reactions leading to the formally aromatic hetero-3,4-dimethylenecyclopentadienediyl derivatives from the thermal rearrangements of (hetero)atom-bridged diallenes (X = CH-, NH, O, S). Protonation of the heteroatom substituent raises the respective 2,6-cyclization energy barrier, and the alternative 1,6-cyclization reaction forming the hetero-cyclohexadienediyl can compete.
Citation Styles
Harvard Citation style: Bui, B. and Schreiner, P. (2006) Thermal rearrangements of heteroatom-bridged diallenes, European Journal of Organic Chemistry, 2006(18), pp. 4187-4192. https://doi.org/10.1002/ejoc.200600270
APA Citation style: Bui, B., & Schreiner, P. (2006). Thermal rearrangements of heteroatom-bridged diallenes. European Journal of Organic Chemistry. 2006(18), 4187-4192. https://doi.org/10.1002/ejoc.200600270
