Journalartikel

Jahr der Veröffentlichung: 2010

Seiten: 2629-2641

Zeitschrift: Journal of Coordination Chemistry

Bandnummer: 63

Heftnummer: 14-16

ISSN: 0095-8972

DOI Link: https://doi.org/10.1080/00958972.2010.490876

Verlag: Taylor and Francis Group

Abstract: 
The ligand L(1) (N1,N3-di[2-di(2-pyridylmethyl)aminoethyl]N1,N3-dimethyl-1,3-propandiamine) bridges two tripodal units of the amine ligand Me(2)uns-penp (N1,N1-dimethyl-N2,N2-di(2-pyridylmethyl)-1,2-ethandiamine) with a propyl group. The ligand L(1), the dinuclear copper(I) complex [Cu(2)(L(1))](BPh(4))(2) and the dinuclear copper(II) complexes [Cu(2)Cl(2)(L(1))](ClO(4))(2), and Cu(2)Cl(2)(L(1))]Cl(2) have been synthesized and structurally characterized. The copper(I) complex reacts reversibly with dioxygen at low temperatures and forms a peroxido complex that is thermally more stable than the related peroxido complex formed from two mononuclear copper(I) complexes of the ligand Me(2)uns-penp.

Harvard-Zitierstil: Wurtele, C., Heinemann, F. and Schindler, S. (2010) Stabilization of a copper peroxido complex with a new binucleating ligand, Journal of Coordination Chemistry, 63(14-16), pp. 2629-2641. https://doi.org/10.1080/00958972.2010.490876

APA-Zitierstil: Wurtele, C., Heinemann, F., & Schindler, S. (2010). Stabilization of a copper peroxido complex with a new binucleating ligand. Journal of Coordination Chemistry. 63(14-16), 2629-2641. https://doi.org/10.1080/00958972.2010.490876