Journal article

Publication year: 2015

Pages: 11103-11106

Journal: Physical Chemistry Chemical Physics

Volume number: 17

Issue number: 16

ISSN: 1463-9076

eISSN: 1463-9084

Open access status: Hybrid

DOI Link: https://doi.org/10.1039/c4cp05737f

Publisher: Royal Society of Chemistry

Abstract: 
Here we show that the Onsager cross terms for ion-electron interactions are not an artifact, but the necessity to phenomenologically and completely describe the mass/charge transport of a mixed ionic-electronic conductor in terms of mobile charged components which are the only experimentally operable species. The use of an appropriate comprehensive defect model may help to reduce the cross terms (which depend on the choice of formal charge of the mobile defects), but it cannot obviate them if long-range Coulombic interactions are in action among the defects.

Harvard Citation style: Yoo, H., Martin, M. and Janek, J. (2015) Comment on "How to interpret Onsager cross terms in mixed ionic electronic conductors" by I. Riess, Phys. Chem. Chem. Phys., 2014, 16, 22513, Physical Chemistry Chemical Physics, 17(16), pp. 11103-11106. https://doi.org/10.1039/c4cp05737f

APA Citation style: Yoo, H., Martin, M., & Janek, J. (2015). Comment on "How to interpret Onsager cross terms in mixed ionic electronic conductors" by I. Riess, Phys. Chem. Chem. Phys., 2014, 16, 22513. Physical Chemistry Chemical Physics. 17(16), 11103-11106. https://doi.org/10.1039/c4cp05737f