Journal article

Publication year: 2016

Pages: 8759-8769

Journal: The Journal of Organic Chemistry

Volume number: 81

Issue number: 19

Open access status: Green

DOI Link: https://doi.org/10.1021/acs.joc.6b01219

Publisher: American Chemical Society

Abstract: 

Direct unequal C–H bond difunctionalization of phosphorylated diamantane
was achieved in high yield from the corresponding phosphonates.
Reduction of the functionalized phosphonates provides access to novel
primary and secondary alkyl/aryl diamantane phosphines. The prepared
primary diamantyl phosphines are quite air stable compared to their
adamantyl and especially alkyl or aryl analogues. This finding is
corroborated by comparing the singly occupied molecular orbital energy
levels of the corresponding phosphine radical cations obtained by
density functional theory computations.

Harvard Citation style: Moncea, O., Gunawan, M., Poinsot, D., Cattey, H., Becker, J., Yurchenko, R., et al. (2016) Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines, The Journal of Organic Chemistry, 81(19), pp. 8759-8769. https://doi.org/10.1021/acs.joc.6b01219

APA Citation style: Moncea, O., Gunawan, M., Poinsot, D., Cattey, H., Becker, J., Yurchenko, R., Butova, E., Hausmann, H., Sekutor, M., Fokin, A., Hierso, J., & Schreiner, P. (2016). Defying Stereotypes with Nanodiamonds: Stable Primary Diamondoid Phosphines. The Journal of Organic Chemistry. 81(19), 8759-8769. https://doi.org/10.1021/acs.joc.6b01219