Journal article

Publication year: 2015

Pages: 3295-3301

Journal: Journal of Coordination Chemistry

Volume number: 68

Issue number: 17-18

DOI Link: https://doi.org/10.1080/00958972.2015.1071802

Publisher: Taylor and Francis Group

Abstract: 

Cage-opened diamondoid tetracyclo[7.3.1.1^4,12.0^2,7]tetradeca-6,11-diene forms complexes with AgNO₃ and CuCl. The latter crystallized from acetonitrile in polymeric form [Cu₂Cl₂(CH₃CN)(diene)]_n; in the presence of 2,2′-bipyridine, a double-charged monomeric Cu(I)-complex [Cu₂(bipy)₂(diene)]²⁺ formed. Both complexes were structurally characterized through X-ray crystal diffraction analysis.                                                                   Copper(I) complexes with the diamantane diene tetracyclo[7.3.1.1^4,12.0^2,7]tetradeca-6.11-diene (6) have been prepared and an interesting crystal structure, [Cu₂(bipy)₂(6)]²⁺ (hydrogen atoms, anions, and solvent molecules are omitted for clarity), was obtained.

Harvard Citation style: Valentin, L., Henss, A., Tkachenko, B., Fokin, A., Schreiner, P., Würtele, C., et al. (2015) Transition metal complexes with cage-opened diamondoid tetracyclo[7.3.1.14,12.02,7]tetradeca-6.11-diene, Journal of Coordination Chemistry, 68(17-18), pp. 3295-3301. https://doi.org/10.1080/00958972.2015.1071802

APA Citation style: Valentin, L., Henss, A., Tkachenko, B., Fokin, A., Schreiner, P., Würtele, C., & Schindler, S. (2015). Transition metal complexes with cage-opened diamondoid tetracyclo[7.3.1.14,12.02,7]tetradeca-6.11-diene. Journal of Coordination Chemistry. 68(17-18), 3295-3301. https://doi.org/10.1080/00958972.2015.1071802