Journal article

Publication year: 2014

Pages: 1678-1688

Journal: Organometallics

Volume number: 33

Issue number: 7

DOI Link: https://doi.org/10.1021/om500014z

Publisher: American Chemical Society

Abstract: 

A series of new adamantane and diamantane hydrazides was synthesized and
coupled with organo-functionalized Sn/S clusters of the general type [R¹Sn₄S₆] (R¹ = CMe₂CH₂COMe)
to form diamondoid-decorated Sn/S clusters. The new ligand precursors
as well as the resulting hybrid compounds were analyzed by NMR
spectroscopy, mass spectrometry, and single-crystal X-ray diffraction,
and first insights were gained in the installation of sterically highly
demanding and at the same time rigid mono-, di-, and trifunctionalized
diamondoid ligands on tetrelchalcogenide cages.

Harvard Citation style: Barth, B., Tkachenko, B., Eußner, J., Schreiner, P. and Dehnen, S. (2014) Diamondoid Hydrazones and Hydrazides: Sterically Demanding Ligands for Sn/S Cluster Design, Organometallics, 33(7), pp. 1678-1688. https://doi.org/10.1021/om500014z

APA Citation style: Barth, B., Tkachenko, B., Eußner, J., Schreiner, P., & Dehnen, S. (2014). Diamondoid Hydrazones and Hydrazides: Sterically Demanding Ligands for Sn/S Cluster Design. Organometallics. 33(7), 1678-1688. https://doi.org/10.1021/om500014z