Journal article

Publication year: 2004

Pages: 4360-4363

Journal: Angewandte Chemie International Edition

Volume number: 43

Issue number: 33

ISSN: 1433-7851

DOI Link: https://doi.org/10.1002/anie.200454125

Publisher: Wiley

Abstract: 

A tale of two modes: An end‐on copper superoxo complex was identified in a combined experimental and theoretical study. Theory clearly discloses the presence of an end‐on complex (see picture, O red, Cu pink, N green) with a minute isotopic resonance Raman splitting below experimental resolution. The results cast doubts on the uncritical use of ¹⁶O,¹⁸O isotopic‐labeling Raman experiments to discriminate end‐on from side‐on bonding modes in M(O₂) complexes.

Harvard Citation style: Schatz, M., Raab, V., Foxon, S., Brehm, G., Schneider, S., Reiher, M., et al. (2004) Combined spectroscopic and theoretical evidence for a persistent end-on copper superoxo complex, Angewandte Chemie International Edition, 43(33), pp. 4360-4363. https://doi.org/10.1002/anie.200454125

APA Citation style: Schatz, M., Raab, V., Foxon, S., Brehm, G., Schneider, S., Reiher, M., Holthausen, M., Sundermeyer, J., & Schindler, S. (2004). Combined spectroscopic and theoretical evidence for a persistent end-on copper superoxo complex. Angewandte Chemie International Edition. 43(33), 4360-4363. https://doi.org/10.1002/anie.200454125