Journalartikel

Jahr der Veröffentlichung: 2016

Seiten: 8764-8773

Zeitschrift: Chemistry of Materials

Bandnummer: 28

Heftnummer: 23

ISSN: 0897-4756

eISSN: 1520-5002

DOI Link: https://doi.org/10.1021/acs.chemmater.6b04175

Verlag: American Chemical Society

Abstract: 
Glassy, glass ceramic, and crystalline lithium thiophosphates have attracted interest in their use as solid electrolytes in all-solid-state batteries. Despite similar structural motifs, including PS43-, P2S64-, and P2S74- polyhedra, these materials exhibit a wide range of possible compositions, crystal structures, and ionic conductivities. Here, we present a combined approach of Bragg diffraction, pair distribution function analysis, Raman spectroscopy, and P-31 magic angle spinning nuclear magnetic resonance spectroscopy to study the underlying crystal structure of Li4P2S6. In this work, we show that the material crystallizes in a planar structural arrangement as a glass ceramic composite, explaining the observed relatively low ionic conductivity, depending on the fraction of glass content. Calculations based on density functional theory provide an understanding of occurring diffusion pathways and ionic conductivity of this Li+ ionic conductor.

Harvard-Zitierstil: Dietrich, C., Sadowski, M., Sicolo, S., Weber, D., Sedlmaier, S., Weldert, K., et al. (2016) Local Structural Investigations, Defect Formation, and Ionic Conductivity of the Lithium Ionic Conductor Li4P2S6, Chemistry of Materials, 28(23), pp. 8764-8773. https://doi.org/10.1021/acs.chemmater.6b04175

APA-Zitierstil: Dietrich, C., Sadowski, M., Sicolo, S., Weber, D., Sedlmaier, S., Weldert, K., Indris, S., Albe, K., Janek, J., & Zeier, W. (2016). Local Structural Investigations, Defect Formation, and Ionic Conductivity of the Lithium Ionic Conductor Li4P2S6. Chemistry of Materials. 28(23), 8764-8773. https://doi.org/10.1021/acs.chemmater.6b04175