Journal article

Unravelling Lawesson's reagent: the structure of monomeric (4-methoxyphenyl)phosphine disulfide


Authors list: Mardyukov, A; Niedek, D; Schreiner, PR

Publication year: 2018

Pages: 2715-2718

Journal: Chemical Communications

Volume number: 54

Issue number: 22

ISSN: 1359-7345

DOI Link: https://doi.org/10.1039/c8cc00034d

Publisher: Royal Society of Chemistry


Abstract: 
We describe the isolation as well as IR and UV/Vis spectroscopic characterization of (4-methoxyphenyl) phosphine disulfide in argon matrices at 10 K. The title compound proved to be highly photolabile; irradiation with UV light (lambda = 334 nm) led to rearrangement to the equally unreported 3-(4-methoxyphenyl)-1,2,3-dithiaphosphirane. Photoreversion can be achieved upon irradiation at lambda = 465 nm.



Citation Styles

Harvard Citation style: Mardyukov, A., Niedek, D. and Schreiner, P. (2018) Unravelling Lawesson's reagent: the structure of monomeric (4-methoxyphenyl)phosphine disulfide, Chemical Communications, 54(22), pp. 2715-2718. https://doi.org/10.1039/c8cc00034d

APA Citation style: Mardyukov, A., Niedek, D., & Schreiner, P. (2018). Unravelling Lawesson's reagent: the structure of monomeric (4-methoxyphenyl)phosphine disulfide. Chemical Communications. 54(22), 2715-2718. https://doi.org/10.1039/c8cc00034d


Last updated on 2025-21-05 at 15:43