Conference paper
Authors list: Zurawski, A; Höller, CJ; Rybak, JC; Müller-Buschbaum, K
Appeared in: Terrae Rarae 2009. Proceedings of the 7th International Conference on f Elements (7 ICfE)
Editor list: Meyer, Gerd
Publication year: 2010
Conference: Terrae Rarae 2009 (7th International Conference on f Elements (7 ICfE), incorporating XXII. Tage der Seltenen Erden)
Reactions of lanthanide metals with self-consuming amine melts of organic ligands can yield a large variety of rare earth amides and amine complexes. The absence of classic solvents directs the reactions towards aggregated systems like coordination polymers and frameworks even together with a high tendency for the formation of homoleptic products. As the absence of solvents does also include the absence of possible co-ligands that otherwise would fill the coordination sphere of the large rare earth ions, it generates reaction conditions that prove especially fruitful to obtain compounds free of unwanted co-ligands. Even more interesting this can go along with a variety of properties like luminescence, high thermal stability or porosity.
Abstract:
Citation Styles
Harvard Citation style: Zurawski, A., Höller, C., Rybak, J. and Müller-Buschbaum, K. (2010) The Solvent Free Melt Synthesis – A Way to Generate Highly Aggregated Systems with Promising Properties, in Meyer, G. (ed.) Terrae Rarae 2009. Proceedings of the 7th International Conference on f Elements (7 ICfE). Bornheim: NWT-Verlag. http://www.uni-koeln.de/math-nat-fak/anorgchem/meyer/icfe/journal/TerraeRaraeOpenAccessJournal2009.pdf
APA Citation style: Zurawski, A., Höller, C., Rybak, J., & Müller-Buschbaum, K. (2010). The Solvent Free Melt Synthesis – A Way to Generate Highly Aggregated Systems with Promising Properties. In Meyer, G. (Ed.), Terrae Rarae 2009. Proceedings of the 7th International Conference on f Elements (7 ICfE). NWT-Verlag. http://www.uni-koeln.de/math-nat-fak/anorgchem/meyer/icfe/journal/TerraeRaraeOpenAccessJournal2009.pdf
