Journalartikel
Autorenliste: Fokin, Andrey A.; Bakhonsky, Vladyslav V.; Pashenko, Alexander E.; Bakhiiev, Emirali; Becker, Jonathan; Kunz, Simon; Schreiner, Peter R.
Jahr der Veröffentlichung: 2023
Seiten: 14172-14177
Zeitschrift: The Journal of Organic Chemistry
Bandnummer: 88
Heftnummer: 19
ISSN: 0022-3263
eISSN: 1520-6904
DOI Link: https://doi.org/10.1021/acs.joc.3c01043
Verlag: American Chemical Society
Abstract:
anti- and syn-sesquihomodiamantenes (SDs) were prepared and structurally characterized. anti-SD and parent sesquihomoadamantene were CH-bond functionalized by utilizing a phase-transfer protocol. The density functional theory-computed ionization potentials of unsaturated diamondoid dimers correlate well with the experimental oxidation potentials obtained from cyclic voltammetry. Similar geometries ensue for both the reduced and ionized SD states, whose persistence is supported by the beta-hydrogen's spatial sheltering. This makes SDs promising building blocks for the construction of diamond materials with high stability and carrier mobility.
Zitierstile
Harvard-Zitierstil: Fokin, A., Bakhonsky, V., Pashenko, A., Bakhiiev, E., Becker, J., Kunz, S., et al. (2023) Synthesis and Functionalization of Isomeric Sesquihomodiamantenes, The Journal of Organic Chemistry, 88(19), pp. 14172-14177. https://doi.org/10.1021/acs.joc.3c01043
APA-Zitierstil: Fokin, A., Bakhonsky, V., Pashenko, A., Bakhiiev, E., Becker, J., Kunz, S., & Schreiner, P. (2023). Synthesis and Functionalization of Isomeric Sesquihomodiamantenes. The Journal of Organic Chemistry. 88(19), 14172-14177. https://doi.org/10.1021/acs.joc.3c01043
Schlagwörter
ADAMANTYLIDENEADAMANTANE; BROMONIUM; ELECTRON; PHOTOEMISSION; RADICAL CATIONS
