Journalartikel

Jahr der Veröffentlichung: 2021

Seiten: 1390-1395

Zeitschrift: Journal of Physical Chemistry Letters

Bandnummer: 12

Heftnummer: 5

ISSN: 1948-7185

DOI Link: https://doi.org/10.1021/acs.jpclett.0c03356

Verlag: American Chemical Society

Abstract: 
The F is core level photoionization of the ionic molecular radical HF+ has been studied using the photon-ion merged-beams technique at a synchrotron radiation source. Upon analyzing kinetic energy release (KER) dependent photoion yield spectra, complex ultrafast dissociation dynamics of the F is core hole excited sigma* state can be revealed. By means of configuration-interaction electronic structure calculations of the excited molecular potential energy curves, this complex process can be attributed to a spin-dependent dissociation of the excited sigma* biradical state.

Harvard-Zitierstil: Martins, M., Reinwardt, S., Schunck, J., Schwarz, J., Baev, K., Müller, A., et al. (2021) Disentangling the Photodissociation Dynamics of the HF+ Molecular Radical via Kinetic-Energy-Release-Resolved F 1s Core Excitation and Ionization, Journal of Physical Chemistry Letters, 12(5), pp. 1390-1395. https://doi.org/10.1021/acs.jpclett.0c03356

APA-Zitierstil: Martins, M., Reinwardt, S., Schunck, J., Schwarz, J., Baev, K., Müller, A., Buhr, T., Perry-Sassmannshausen, A., Klumpp, S., & Schippers, S. (2021). Disentangling the Photodissociation Dynamics of the HF+ Molecular Radical via Kinetic-Energy-Release-Resolved F 1s Core Excitation and Ionization. Journal of Physical Chemistry Letters. 12(5), 1390-1395. https://doi.org/10.1021/acs.jpclett.0c03356