Journal article

Publication year: 2020

Journal: Journal of Membrane Science

Volume number: 610

ISSN: 0376-7388

eISSN: 1873-3123

DOI Link: https://doi.org/10.1016/j.memsci.2020.118254

Publisher: Elsevier

Abstract: 
Hydroxide ion conductive polymer coatings with a low permeability for zinc species reduce shape change and dendrite formation of zinc anodes, and reduce the capacity fade over charge/discharge cycles. Herein we focus on the material properties and aim to minimize the permeability of polybenzimidazole (PBI) for zincate ions by methylating its imidazole NH groups. This reduces the volume swelling in 4 M KOH solution from 104% for PBI to 20% for a PBI with 1.3 methyl groups per repeat unit. Similarly, materials with a degree of methylation (DOM) between 0.96 and 1.2 show very low uptake of KOH. Above a DOM of 1.7 decreasing alkaline stability is observed, presumably because a fraction of the imidazole groups is permethylated to benzmidazolium ions. Most importantly, membranes with a DOM around 1-1.2 revealed the lowest permeation for zincate ions, with permeability coefficients P of 0.9-1.5 10(-9) cm(2) s(-1), 3000 times lower than for PBI. At higher DOM slightly higher P values were observed. In a Zn/NiOOH cell an optimized anode coating with 0.96MePBI led to better cycling stability than with PBI, and an initial capacity of 265 mAh (g anode)(-1).

Harvard Citation style: Konovalova, A., Stock, D., Schroeder, S., Park, H., Jang, J., Kim, H., et al. (2020) Partially methylated polybenzimidazoles as coating for alkaline zinc anodes, Journal of Membrane Science, 610, Article 118254. https://doi.org/10.1016/j.memsci.2020.118254

APA Citation style: Konovalova, A., Stock, D., Schroeder, S., Park, H., Jang, J., Kim, H., Han, J., Schroeder, D., & Henkensmeier, D. (2020). Partially methylated polybenzimidazoles as coating for alkaline zinc anodes. Journal of Membrane Science. 610, Article 118254. https://doi.org/10.1016/j.memsci.2020.118254