Journal article

Publication year: 2019

Pages: 16505-16514

Journal: Physical Chemistry Chemical Physics

Volume number: 21

Issue number: 30

ISSN: 1463-9076

eISSN: 1463-9084

Open access status: Hybrid

DOI Link: https://doi.org/10.1039/c9cp02864a

Publisher: Royal Society of Chemistry

Abstract: 
Ion yields following X-ray absorption of the cationic series NHy+ (y = 0-3) were measured to identify the characteristic absorption resonances in the energy range of the atomic nitrogen K-edge. Significant changes in the position of the absorption resonances were observed depending on the number of hydrogen atoms bound to the central nitrogen atom. Configuration interaction (CI) calculations were performed to obtain line assignments in the frame of molecular group theory. To validate the calculations, our assignment for the atomic cation N+, measured as a reference, was compared with published theoretical and experimental data.

Harvard Citation style: Bari, S., Inhester, L., Schubert, K., Mertens, K., Schunck, J., Doerner, S., et al. (2019) Inner-shell X-ray absorption spectra of the cationic series NHy+ (y = 0–3), Physical Chemistry Chemical Physics, 21(30), pp. 16505-16514. https://doi.org/10.1039/c9cp02864a

APA Citation style: Bari, S., Inhester, L., Schubert, K., Mertens, K., Schunck, J., Doerner, S., Deinert, S., Schwob, L., Schippers, S., Müller, A., Klumpp, S., & Martins, M. (2019). Inner-shell X-ray absorption spectra of the cationic series NHy+ (y = 0–3). Physical Chemistry Chemical Physics. 21(30), 16505-16514. https://doi.org/10.1039/c9cp02864a