Journal article

Publication year: 2019

Pages: 2106-2113

Journal: Chemistry of Materials

Volume number: 31

Issue number: 6

ISSN: 0897-4756

eISSN: 1520-5002

DOI Link: https://doi.org/10.1021/acs.chemmater.9b00001

Publisher: American Chemical Society

Abstract: 
Crystalline materials with ultralow thermal conductivity are essential for thermal barrier coating and thermoelectric energy conversion. Nontoxic n-type bulk cubic AgBiS2 exhibits exceptionally low lattice thermal conductivity (kappa(lat)) of 0.68-0.48 W/m K in the temperature range of 298-820 K, which is near the theoretical minimum (kappa(min)). The low kappa(lat) is attributed to soft vibrations of predominantly Ag atoms and significant lattice anharmonicity because of local structural distortions along the [011] direction, arising because of the stereochemical activity of the 6s(2) lone pair of Bi, as suggested by pair distribution function analysis of the synchrotron X-ray scattering data. The low-temperature heat capacity of AgBiS2 shows a broad hump because of the Ag-induced low-energy Einstein modes as also suggested from phonon dispersion calculated by first-principle density functional theory. Low-energy optical phonons contributed by Ag and Bi strongly scatter heat-carrying acoustic phonons, thereby decreasing the kappa(lat) to a low value. A maximum thermoelectric figure of merit of similar to 0.7 is attained at 820 K for bulk spark plasma-sintered n-type AgBiS2.

Harvard Citation style: Rathore, E., Juneja, R., Culver, S., Minafra, N., Singh, A., Zeier, W., et al. (2019) Origin of Ultralow Thermal Conductivity in n-Type Cubic Bulk AgBiS₂: Soft Ag Vibrations and Local Structural Distortion Induced by the Bi 6s² Lone Pair, Chemistry of Materials, 31(6), pp. 2106-2113. https://doi.org/10.1021/acs.chemmater.9b00001

APA Citation style: Rathore, E., Juneja, R., Culver, S., Minafra, N., Singh, A., Zeier, W., & Biswas, K. (2019). Origin of Ultralow Thermal Conductivity in n-Type Cubic Bulk AgBiS₂: Soft Ag Vibrations and Local Structural Distortion Induced by the Bi 6s² Lone Pair. Chemistry of Materials. 31(6), 2106-2113. https://doi.org/10.1021/acs.chemmater.9b00001