Journalartikel

Jahr der Veröffentlichung: 2018

Seiten: 1791-1798

Zeitschrift: Chemistry of Materials

Bandnummer: 30

Heftnummer: 5

ISSN: 0897-4756

eISSN: 1520-5002

DOI Link: https://doi.org/10.1021/acs.chemmater.8b00266

Verlag: American Chemical Society

Abstract: 
The lithium-ion conductor Li10GeP2S12 (LGPS) is known to exhibit ionic conductivity values as high as 12 mS.cm(-1). Unfortunately, counter to chemical intuition, many attempts to enhance the ionic transport in LGPS, e.g., by increasing the Sn fraction in Li10Ge1-xSnxP2S12, have even led to a reduction in the conductivity. Employing a combination of Rietveld refinements against X-ray diffraction data, speed of sound measurements, and electrochemical impedance spectroscopy, we investigate the structure-property relationships governing this behavior. Herein, it is shown that with increasing Sn4+ fraction in Li10Ge1-xSnxP2S12 a structural bottleneck along the diffusion channels in the z-direction begins to tighten, and with the concomitant increase in the lattice softness, the local ionic bonding interactions between Li+ and S2- become stronger, further increasing the activation barrier. This work provides a likely explanation for the lower conductivity exhibited by Li10SnP2S12 and demonstrates that there is more to the underlying lithium diffusion mechanism in the Li10MP2S12 structure.

Harvard-Zitierstil: Krauskopf, T., Culver, S. and Zeier, W. (2018) Bottleneck of Diffusion and Inductive Effects in Li₁₀Ge_1-xSn_xP₂S₁₂, Chemistry of Materials, 30(5), pp. 1791-1798. https://doi.org/10.1021/acs.chemmater.8b00266

APA-Zitierstil: Krauskopf, T., Culver, S., & Zeier, W. (2018). Bottleneck of Diffusion and Inductive Effects in Li₁₀Ge_1-xSn_xP₂S₁₂. Chemistry of Materials. 30(5), 1791-1798. https://doi.org/10.1021/acs.chemmater.8b00266