Journal article

Publication year: 2017

Pages: 1508-1512

Journal: Journal of Inorganic and General Chemistry

Volume number: 643

Issue number: 21

ISSN: 0044-2313

eISSN: 1521-3749

Open access status: Bronze

DOI Link: https://doi.org/10.1002/zaac.201700252

Publisher: Wiley

Abstract: 
The reaction of [((RSn)-Sn-1)(3)Se4Cl] (R-1 = CMe2CH2COMe) with [Pd(PPh3)(2)Cl-2], (SiMe3)(2)Se, and hydrazine hydrate yields a new Pd/Se cluster, [Pd-3(PPh3)(5)(SeH)(mu(3)-Se)(2)][SnCl3] (1). Using [((RSn)-Sn-1)(4)Se-6] as reactant and varying the reaction conditions as well as the addition of (SiMe3)(2)Se and hydrazine hydrate, [Pd-3(PPh3)(5)(SnCl3)(mu(3)-Se)(2)][SnCl3] (2) and [Pd-2(PPh3)(3)Cl{SnR2Cl2}(mu(3)-Se)(2)] (3) can be isolated. 3 is the first compound based on a [Pd2SnSe2] moiety, which furthermore exhibits a functional organic group at the tin atom. Its photoluminescence and absorption spectra are discussed as well. All compounds were characterized by single-crystal X-ray diffraction, indicating a bi-pyramidal structure. Mass spectrometric analyses of the reaction solutions provide some insight into the formation of the clusters.

Harvard Citation style: Rinn, N., Hanau, K., Guggolz, L., Rinn, A., Chatterjee, S. and Dehnen, S. (2017) Trigonal Bipyramidal Metalselenide Clusters with Palladium and Tin Atoms in Various Positions, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 643(21), pp. 1508-1512. https://doi.org/10.1002/zaac.201700252

APA Citation style: Rinn, N., Hanau, K., Guggolz, L., Rinn, A., Chatterjee, S., & Dehnen, S. (2017). Trigonal Bipyramidal Metalselenide Clusters with Palladium and Tin Atoms in Various Positions. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 643(21), 1508-1512. https://doi.org/10.1002/zaac.201700252