Journal article
Authors list: Schindler, Lisa Verena; Wickleder, Mathias S.
Publication year: 2017
Pages: 63-68
Journal: A Journal of Chemical Sciences
Volume number: 72
Issue number: 1
ISSN: 0932-0776
eISSN: 1865-7117
DOI Link: https://doi.org/10.1515/znb-2016-0159
Publisher: De Gruyter
Abstract:
Rb-3[H(HSO4)(2)][S2O7] (monoclinic, C2/c (no. 15), a = 1638.75(6), b = 768.52(3), c = 1187.88(4) pm, beta = 106.805(2)degrees, V = 1432.14(9) center dot 10(6) pm, Z = 4) was obtained from the reaction of Rb-2[CO3] (99.9%, not dried, 150 mg, 0.6 mmol) with neat SO3 in a torch-sealed glass ampoule. The remaining quantity of water in the starting material was obviously sufficient to lead to an H-containing substance. The structure shows the unprotonated disulfate anion [S2O7](2-) adjacent to the hydrogenium- bis- hydrogensulfate anion [H(HSO4)(2)](-) with the central hydrogen atom located close to a center of inversion.
Citation Styles
Harvard Citation style: Schindler, L. and Wickleder, M. (2017) Hydrogenium-bis-hydrogensulfate anions adjacent to [S2O7]2- in Rb3[S2O7][H(HSO4)2]:a structural evidence of the increasing acidity of polysulfuric acids with growing chain length, Zeitschrift fur Naturforschung B, 72(1), pp. 63-68. https://doi.org/10.1515/znb-2016-0159
APA Citation style: Schindler, L., & Wickleder, M. (2017). Hydrogenium-bis-hydrogensulfate anions adjacent to [S2O7]2- in Rb3[S2O7][H(HSO4)2]:a structural evidence of the increasing acidity of polysulfuric acids with growing chain length. Zeitschrift fur Naturforschung B. 72(1), 63-68. https://doi.org/10.1515/znb-2016-0159
Keywords
disulfate; hydrogenium-bis-hydrogensulfate; KHSO4; NH4; PHASE-TRANSITIONS; polysulfate; POTASSIUM HYDROGENSULFATE; RB
