Journalartikel

Peripheral ligands as electron storage reservoirs and their role in enhancement of photocatalytic hydrogen generation


AutorenlistePan, Qing; Freitag, Leon; Kowacs, Tanja; Falgenhauer, Jane C.; Korterik, Jeroen P.; Schlettwein, Derck; Browne, Wesley R.; Pryce, Mary T.; Rau, Sven; Gonzalez, Leticia; Vos, Johannes G.; Huijser, Annemarie

Jahr der Veröffentlichung2016

Seiten9371-9374

ZeitschriftChemical Communications

Bandnummer52

Heftnummer60

ISSN1359-7345

eISSN1364-548X

Open Access StatusHybrid

DOI Linkhttps://doi.org/10.1039/c6cc05222c

VerlagRoyal Society of Chemistry


Abstract
The contrasting early-time photodynamics of two related Ru/Pt photocatalysts with very different photocatalytic H-2 generation capabilities are reported. Ultrafast equilibration (535 +/- 17 fs) creates an electron reservoir on the peripheral ligands of the ester substituted complex, allowing a dramatic increase in photocatalytic performance. This insight opens the way towards a novel design strategy for H-2 generating molecular photocatalysts.



Autoren/Herausgeber




Zitierstile

Harvard-ZitierstilPan, Q., Freitag, L., Kowacs, T., Falgenhauer, J., Korterik, J., Schlettwein, D., et al. (2016) Peripheral ligands as electron storage reservoirs and their role in enhancement of photocatalytic hydrogen generation, Chemical Communications, 52(60), pp. 9371-9374. https://doi.org/10.1039/c6cc05222c

APA-ZitierstilPan, Q., Freitag, L., Kowacs, T., Falgenhauer, J., Korterik, J., Schlettwein, D., Browne, W., Pryce, M., Rau, S., Gonzalez, L., Vos, J., & Huijser, A. (2016). Peripheral ligands as electron storage reservoirs and their role in enhancement of photocatalytic hydrogen generation. Chemical Communications. 52(60), 9371-9374. https://doi.org/10.1039/c6cc05222c



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