Journalartikel

Thermoelectric transport and microstructure of optimized Mg2Si0.8Sn0.2


Autorenlistede Boor, J.; Gupta, S.; Kolb, H.; Dasgupt, T.; Mueller, E.

Jahr der Veröffentlichung2015

Seiten10467-10475

ZeitschriftJournal of Materials Chemistry C Materials for optical and electronic devices

Bandnummer3

Heftnummer40

ISSN2050-7526

eISSN2050-7534

Open Access StatusHybrid

DOI Linkhttps://doi.org/10.1039/c5tc01535a

VerlagRoyal Society of Chemistry


Abstract
Solid solutions of magnesium silicide and magnesium stannide exhibit excellent thermoelectric properties due to favorable electronic band structures and reduced thermal conductivity compared to the binary compounds. We have optimized the composition Mg2Si0.8Sn0.2 by Sb doping and obtained a thermoelectric figure of merit close to unity. The material comprises of several phases and exhibits intrinsic nanostructuring. Nevertheless, the main features of electronic transport can be understood within the framework of a single parabolic band model. Compared to Mg2Si we observe a comparable power factor, a drastically reduced thermal conductivity and an increased effective mass.



Zitierstile

Harvard-Zitierstilde Boor, J., Gupta, S., Kolb, H., Dasgupt, T. and Mueller, E. (2015) Thermoelectric transport and microstructure of optimized Mg2Si0.8Sn0.2, Journal of Materials Chemistry C Materials for optical and electronic devices, 3(40), pp. 10467-10475. https://doi.org/10.1039/c5tc01535a

APA-Zitierstilde Boor, J., Gupta, S., Kolb, H., Dasgupt, T., & Mueller, E. (2015). Thermoelectric transport and microstructure of optimized Mg2Si0.8Sn0.2. Journal of Materials Chemistry C Materials for optical and electronic devices. 3(40), 10467-10475. https://doi.org/10.1039/c5tc01535a



Schlagwörter


ELASTIC-CONSTANTSLATTICE VIBRATION FREQUENCIESMG2SI


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