Journal article

Publication year: 2015

Pages: 519-527

Journal: Materials Horizons

Volume number: 2

Issue number: 5

ISSN: 2051-6347

eISSN: 2051-6355

Open access status: Green

DOI Link: https://doi.org/10.1039/c5mh00033e

Publisher: Royal Society of Chemistry

Abstract: 
Engineering of nanoscaled structures may help controlling the electrical and thermal transport in solids, in particular for thermoelectric applications that require the combination of low thermal conductivity and low electrical resistivity. The tetragonal tungsten bronzes Nb8-xW9+xO47 (TTB) allow a continuous variation of the charge carrier concentration while fulfilling at the same time the concept of a "phonon-glass electron-crystal'' through a layered nanostructure defined by intrinsic crystallographic shear planes. The thermoelectric properties of the tetragonal tungsten bronzes Nb8-xW9+xO47 -delta (0 < x < 2) were studied in the temperature range from 373 to 973 K. Structural defects and the thermal stability under various oxygen partial pressure pO(2) were investigated by means of thermogravimetry, HR-TEM, and XRD. Nb8W9O47-delta was found stable at 973 K and a pO(2) of approximate to 10(-15) atm. The oxygen nonstoichiometry delta can reach up to 0.3, depending on the applied atmosphere. By increasing the substitution level x, the electrical resistivity rho and the Seebeck coefficient S decreased. For x = 2, rho reached 20 m Omega cm at 973 K, combined with a Seebeck coefficient of approximately -120 mu V K-1. The thermal conductivity was low for all samples, ranging from 1.6 to 2.0 W K-1 m(-1), attributed to the complex crystal structure. The best thermoelectric figure of merit zT of the investigated samples was 0.043, obtained for x = 2 at 973 K, but it is expected to increase significantly upon a further increase of x. The control of the oxygen non-stoichiometry delta opens a second independent optimization strategy for tetragonal tungsten bronzes.

Harvard Citation style: Heinrich, C., Schrade, M., Cerretti, G., Lieberwirth, I., Leidich, P., Schmitz, A., et al. (2015) Tetragonal tungsten bronzes Nb_8-xW_9+xO_47-δ: optimization strategies and transport properties of a new n-type thermoelectric oxide, Materials Horizons, 2(5), pp. 519-527. https://doi.org/10.1039/c5mh00033e

APA Citation style: Heinrich, C., Schrade, M., Cerretti, G., Lieberwirth, I., Leidich, P., Schmitz, A., Fjeld, H., Mueller, E., Finstad, T., Norby, T., & Tremel, W. (2015). Tetragonal tungsten bronzes Nb_8-xW_9+xO_47-δ: optimization strategies and transport properties of a new n-type thermoelectric oxide. Materials Horizons. 2(5), 519-527. https://doi.org/10.1039/c5mh00033e